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藥物食品分析 MEDLINESCIEScopus

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篇名 TEST_超臨界二氧化碳萃取紅檜木屑之成分分析研究:和水蒸氣蒸餾法及溶劑萃取法相比較
卷期 4:3
並列篇名 Supercritical Carbon Dioxide Extraction of Red Cypress Sawdust: A Comparison of Solvent Extraction vs. Steam Distillation Methods
作者 傅明仁呂冠霆柯淑惠潘懷宗
頁次 203-214
關鍵字 超臨界二氧化碳萃取水蒸氣蒸餾法氣相層析質譜術紅檜木屑Gas chromatography/mass spectrometrySupercritical extractionSteam distillationRed cypress sawdustGas chromatography/mass spectrometrySupercritical extractionSteam distillationRed cypress sawdustMEDLINEScopusSCIE
出刊日期 199609

中文摘要

本實驗主要目的有二:第一是利用較先進且較符合環保要求的萃取方法-超臨界二氧化碳萃取法(SFE-CO2),對紅檜木屑進行萃取。第二是配合其它不同的萃取方法,包括溶劑萃取法、水蒸氣蒸餾法以及頂空氣相法,來和SFE-CO2進行比較分析,這樣才能進一步了解SFE-CO2的萃取特性。紅檜木屑分別經各種不同的萃取方法萃取之後,注入氣相層析/質譜儀進行分析,再以資料庫搜尋系統(Library search)做比對,並比較其結果。結果顯示(1)對萃取檜木而言,二氧化碳在35℃、3000psi下,其極性是介於乙醚和水之間。(2)因為當使用n-hexane來萃取時,所得之peak數目很少,且Abundance非常的低,所以顯示檜木之木屑中絕大部分是屬於極性物質。最後由於SFE-CO2萃取沒有一個完美的經驗公式能夠計算任一物質的萃取率,所以針對每一物質萃取所得到的結果,均有其參考及利用之價值,尤其是目前以SFE-CO2萃取台灣本土植物的資料庫依然貧乏之際,更是值得大家用心去灌溉。

英文摘要

By using a supercritical carbon dioxide extraction (SFE-CO2) technique. We extracted several fragrances from red cypress sawdust under a condition of 3500 psi and 35℃. The extracts were then analyzed by a gas chromatography/masss pectrometry (GC/MS). After a Wiley mass spectrum library search, We identified most of the major peaks in the GC/MS totalion chromatogram, which are borneol,myrtenol, β-elemene, β-selinene, S-cadinene, and α-pinene, etc. for a total of 26 different compounds. In comparison with n-hexane extraction, ether extraction, steam distillation, and head space sampling techniques, we concluded that(1) the polarity of CO2 under the condition of 3500 psi and 35℃ is between ether and water; and(2) most of the fragrances in the cypress sawdust are polar compounds.

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