篇名 | 以石墨爐式原子吸收光譜法測定食用油脂類中銅之含量 |
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卷期 | 7:3 |
並列篇名 | Determination of Copper in Edible Oils by Direct Graphite Furnace Atomic Absorption Spectrometry |
作者 | 陳石松 、 陳清美 、 鄭秋真 、 周薰修 |
頁次 | 207-214 |
關鍵字 | 石墨爐式原子吸收光譜儀 、 銅 、 食用油脂 、 Graphite furnace atomic absorption spectrophotometer 、 Copper 、 Edible oils and fats 、 MEDLINE 、 Scopus 、 SCIE |
出刊日期 | 199909 |
本研究探討以石墨爐式原子吸收光譜儀直接分析食用油脂類中之銅含量,將檢體以2%lecithin-cyclohexane溶液等量稀釋後,以偏極化茲曼石墨爐式原子吸收光譜儀直接檢測,得知最適灰化溫度為900℃,最適原子化溫度為2700℃。銅標準溶液之稀釋液為2%lecithin-cyclohexane優於沙拉油和cyclohexane。Lecithin在cyclohexane之濃度高於2%時,吸光度檢測狀況最佳。本方法之油脂樣品偵測極限為2.0 ng/mL,其次,添加銅10,20及40ng/mL於大豆沙拉油中,使用標準添加法測定,其回收率為85.5%-90.0%。添加於豬油中,回收率為86.0%-93.0%。
A simple method for determination of copper in edible oils was developed,using a polarized Zeeman graphite furnace atomic absorption spectrophotometer anda pyro graphite tube. Edible oils were diluted with 2 % lecithin-cyclohexane andanalyzed directly by the standard addition method. The optimal ashing and atomizingtemperatures were 900℃ and 2700℃, respectively. A standard solution diluted with2% lecithin-cyclohexane was superior to salad oil or cyclohexane. Results were bestmeasured when the concentration of lecithin in cyclohexane was higher than 2%. Thedetection limit of this method was 2.0 ng/mL. The respective range of recovery ofcopper was 85.5-90.0% and 86.0-93.0% in salad oil and lard which were fortified with10, 20 and 40 ng Cu/mL respectively using the standard addition method.