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界面科學會誌

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篇名 Water-borne Acrylic Pressure-Sensitive Adhesives Prepared by Using Cationic Surfactant
卷期 26:3
並列篇名 陽離子性界面活性劑安定之聚丙烯酸酯乳液感壓接著性質
作者 朱侯憲賴孟邦
頁次 129-138
關鍵字 陽離子性界面活性劑丙烯酸酯乳液感壓接著劑CationicSurfactantAcrylicLatexPressure-sensitive adhesive
出刊日期 200409

中文摘要

     使用陽離子性界面活性劑(十六烷基三甲基溴化銨,CTAB)於甲基丙烯酸甲酯(MMA)與丙烯酸-2-乙基,己基酯(2-EHA)為主成分之乳化共聚合(於65℃),順利製備水性感壓膠。此乳液具有甚高的黏度(對水相對黏度達7,700),遠高於陰離子性界面活性劑(十二烷基硫酸鈉,SDS)所製備之乳液。而且,不同之界面活性劑系統所製備黏劑具有迥異之極限黏度、速黏性、剪切與剝離強度。

英文摘要

     The latex pressure-sensitive adhesive (PSA) was prepared successfully by using cationic surfactant (cetyltrimethylammonium bromide, CTAB) in the emulsion copolymerization of methyl methacrylate (MMA) and 2-ethylhexyl acrylate (2-EHA) at 65℃. The latex prepared by using cationic surfactant exhibited quite high a viscosity (the relative viscosity being as high as 7,700), much higher than that prepared by using anionic surfactant (sodium dodecyl sulfate, SDS). Besides, different surfactant systems produced the adhesives having tremendously different values in intrinsic viscosity, tack, shear strength and peel strength.

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