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臺灣農業化學與食品科學 Scopus
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| 篇名 | 台灣蚤休(Paris formosana Hayata)類固醇皂苷的分離與鑑定 |
|---|---|
| 卷期 | 48:6 |
| 並列篇名 | Isolation and Identification of Steroidal Saponins in Taiwanese Rhizoma Paridis Cultivar (Paris formosana Hayata) |
| 作者 | 楊 登 傑 、 張 耀 仁 、 劉 世 詮 、 呂 美 鵬 、 林 昭 田 |
| 頁次 | 289-300 |
| 關鍵字 | Paris formosana Hayata 、 furostanol glycoside 、 spirostanol glycoside 、 pennogenin 、 diosgenin 、 Scopus 、 TSCI |
| 出刊日期 | 201012 |
中文摘要
台灣蚤休 (Paris formosana Hayata) 具有九個類固醇皂苷，其化學結構是利用液-液萃取配合高效能液相層析儀進行分離純化，再經液相層析質譜儀與核磁共振儀進行結構鑑定得知。此九個類固醇皂苷包括三個furostanol glycosides: 26-O-β-D-glucopyranosyl-22α
methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-Dglucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside和26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy-(1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside, 二個pennogenyl glycosides (spirostanol glycosides): 25(R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside和(25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D
(25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L
rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)]-β-D
glucopyranoside, (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside (25R)-spirost-5-en-3β-ol和(25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D
glucopyranoside.
英文摘要
Nine steroidal saponins were found in Taiwanese Rhizoma Paridis cultivar (Paris formosana Hayata). They were isolated through liquid-liquid partition and high performance liquid chromatography (HPLC), and identified by NMR and HPLC-Mass. The nine saponins included three furostanol glycosides: 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside and 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy-(1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside, two pennogenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside and (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside, and four diosgenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, (25R)-spirost-5-en-3β-ol (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)]-β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside and (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside.