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篇名 以奈米改質多孔性氧化鋁為基礎的重金屬離子吸附分離技術
卷期 35:3=197
並列篇名 Heavy Metal Ions Adsorption and Separation Based on Modifi ed Nanoporous Anodic Aluminum Oxide Structures
作者 張興政陳雅惠羅安婷
頁次 046-054
出刊日期 201312

中文摘要

本裝置採用陽極處理與薄膜改質技術,製作奈微米多孔性改質氧化鋁(AAO)過濾膜感測結構,可有效吸附分離溶液重金屬離子。設計化學發光檢測機制整合於立體微流檢測系統,實驗檢測市售彩妝化妝品重金屬含量。採用化學沉積法分別將聚羅丹寧、活性氧化鋁與活性碳三種吸附劑聚合於AAO膜多孔表面與孔洞側壁,形成具多吸附性分離之多孔吸附AAO複合膜,改質AAO複合膜具有良好的孔洞均勻性、高孔隙率、特異吸附性和良好的透水性,能有效提高AAO膜表面吸附與分離金屬離子能力。

英文摘要

The modified nanoporous Anodic aluminum oxiae (AAO) as sensing structures for adsorption of heavy metal ions removal from aqueous solution was developed by two-step anodization and surface modification processes. The chemiluminescence (CL) reaction of luminol-based mechanism for measuring selected ions concentration was achieved by using a three dimensional stacked centrifugal microfluidic system. The adsorbents of rhodanine monomer, activated alumina and activated carbon were immobilized onto the surface and internal pores of nanoporous AAO template as multi-filtration modified-AAO composite membrane exhioited excellent uniformities, high surface porosity, low nonspecific adsorption and good hydraulic permeability and can be used for enhancing adsorption and separation of heavy metal ions.

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