本文簡介以低溫高磁場X光吸收能譜來研究BaCoO₃及TbFe₃(BO₃)₄。前者的有效磁矩大於1.73μB，暗示非零的軌道磁矩，然而其晶體結構傾向磁量子數為零的基態；藉由X光磁圓偏振二向性實驗與理論模擬，我們發現Co之間的交互作用會造成能階的反轉，導致Co具有非零的軌道磁矩。後者在低溫會轉變為反鐵磁相，因Tb與Fe皆具有磁矩，我們利用X光線偏振二向性實驗確認其反鐵磁結構；此外，我們亦在不同磁場下進行實驗，以釐清其磁化量突然抬升背後的機制。

In this manuscript, the X-ray absorption spectroscopy studies on BaCoO₃ and TbFe₃(BO₃)₄ under high magnetic field are briefly introduced. For BaCoO₃, the effective magnetic moment (2.23 μ B) extracted from the magnetic susceptibility is larger than 1.73 μ B (the value without any orbital moment), while its crystal structure prefers the hole occupation of the a1g orbital with m = 0. Combining the X-ray magnetic circular dichroism and theoretical calculations, we found that the short distance between Co ions along the c axis makes the a1g orbital lower in energy and thus leads to the finite orbital moment. On the other hand, we employed X-ray linear dichroism to determine the antiferromagnetic structure of TbFe₃(BO₃)₄ and performed experiments under various magnetic field to investigate the significant enhancement of the magnetization in the antiferromagnetic phase.